Intramolecular arylation of amino acid enolates.
نویسندگان
چکیده
Dianionic enolates formed from N'-aryl urea derivatives of amino acids undergo intramolecular C-arylation by attack of the enolate anion on the N'-aryl ring, leading to a hydantoin derivative of a quaternary amino acid. In situ IR studies allow identification of four intermediates on the reaction pathway.
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ورودعنوان ژورنال:
- Chemical communications
دوره 49 84 شماره
صفحات -
تاریخ انتشار 2013